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SCIENCE CHINA Materials, Volume 61, Issue 10: 1285-1290(2018) https://doi.org/10.1007/s40843-018-9259-4

High-capacity organic electrode material calix[4]quinone/CMK-3 nanocomposite for lithium batteries

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  • ReceivedFeb 1, 2018
  • AcceptedMar 21, 2018
  • PublishedApr 20, 2018

Abstract

Organic lithium-ion batteries (OLIBs) represent a new generation of power storage approach for their environmental benignity and high theoretical specific capacities. However, it has the disadvantage with regard to the dissolution of active materials in organic electrolyte. In this study, we encapsulated high capacity material calix[4]quinone (C4Q) in the nanochannels of ordered mesoporous carbon (OMC) CMK-3 with various mass ratios ranging from 1:3 to 3:1, and then systematically investigated their morphology and electrochemical properties. The nanocomposites characterizations confirmed that C4Q is almost entirely capsulated in the nanosized pores of the CMK-3 while the mass ratio is less than 2:1. As cathodes in lithium-ion batteries, the C4Q/CMK-3 (1:2) nanocomposite exhibits optimal initial discharge capacity of 427 mA h g−1 with 58.7% cycling retention after 100 cycles. Meanwhile, the rate performance is also optimized with a capacity of 170.4 mA h g−1 at 1 C. This method paves a new way to apply organic cathodes for lithium-ion batteries.


Funded by

the National Natural Science Foundation of China(21403187)

the Natural Science Foundation of Hebei Province of China(B2015203124)

the Key Laboratory of Advanced Energy Materials Chemistry(Ministry,of,Education)

Naikai University.


Acknowledgment

This work was supported by the National Natural Science Foundation of China (21403187), the Natural Science Foundation of Hebei Province of China (B2015203124) and the Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University.


Interest statement

These authors declare no conflict of interest.


Contributions statement

Zheng S wrote the paper. Hu J and Yan B prepared the calix[4]quinone (C4Q). Zheng S, Hu J collected the data and analyzed the results. Sun H provided the glovebox for cell assembling and TEM, FTIR, NMR tests. Huang W supervised the project, conceived the experiments, analyzed the results and wrote the paper. All authors contributed to the general discussion.


Author information

Shibing Zheng obtained his BSc degree at Hebei University of Engineering in China in 2015. He is currently a master candidate in Prof. Weiwei Huang’s group at Yanshan University. His research focuses on the synthesis and fabrication of polymer electrode materials for Li/Na battery.


Weiwei Huang obtained her BSc degree at Hebei Normal University of Science & Technology in China in 2005, MSc degree in inorganic chemistry at Hebei Normal University in 2008, and completed her PhD in physical chemistry at Nankai University in 2011. Then, she joined Prof. Chen Jun’s group at Nankai University as a postdoctoral fellow. Since 2013, she joined the School of Environmental and Chemical Engineering at Yanshan University (Qinhuangdao) as an associate professor. Her research is focused on the organic electrode materials for Li/Na battery.


Supplement

Supplementary information

Supporting data are available in the online version of the paper.


References

[1] Kim SW, Seo DH, Ma X, et al. Electrode materials for rechargeable sodium-ion batteries: potential alternatives to current lithium-ion batteries. Adv Energy Mater, 2012, 2: 710-721 CrossRef Google Scholar

[2] Liang Y, Tao Z, Chen J. Organic electrode materials for rechargeable lithium batteries. Adv Energy Mater, 2012, 2: 742-769 CrossRef Google Scholar

[3] Shi Y, Peng L, Ding Y, et al. Nanostructured conductive polymers for advanced energy storage. Chem Soc Rev, 2015, 44: 6684-6696 CrossRef PubMed Google Scholar

[4] Zhang K, Hu Z, Tao Z, et al. Inorganic & organic materials for rechargeable Li batteries with multi-electron reaction. Sci China Mater, 2014, 57: 42-58 CrossRef Google Scholar

[5] Wang C, Wang L, Li F, et al. Bulk bismuth as a high-capacity and ultralong cycle-life anode for sodium-ion batteries by coupling with glyme-based electrolytes. Adv Mater, 2017, 29: 1702212 CrossRef PubMed Google Scholar

[6] Song Z, Zhou H. Towards sustainable and versatile energy storage devices: an overview of organic electrode materials. Energy Environ Sci, 2013, 6: 2280 CrossRef Google Scholar

[7] Nokami T, Matsuo T, Inatomi Y, et al. Polymer-bound pyrene-4,5,9,10-tetraone for fast-charge and -discharge lithium-ion batteries with high capacity. J Am Chem Soc, 2012, 134: 19694-19700 CrossRef PubMed Google Scholar

[8] Song Z, Qian Y, Gordin ML, et al. Polyanthraquinone as a reliable organic electrode for stable and fast lithium storage. Angew Chem Int Ed, 2015, 54: 13947-13951 CrossRef PubMed Google Scholar

[9] Xie J, Wang Z, Gu P, et al. A novel quinone-based polymer electrode for high performance lithium-ion batteries. Sci China Mater, 2016, 59: 6-11 CrossRef Google Scholar

[10] Morita Y, Nishida S, Murata T, et al. Organic tailored batteries materials using stable open-shell molecules with degenerate frontier orbitals. Nat Mater, 2011, 10: 947-951 CrossRef PubMed ADS Google Scholar

[11] Milczarek G, Inganäs O. Renewable cathode materials from biopolymer/conjugated polymer interpenetrating networks. Science, 2012, 335: 1468-1471 CrossRef PubMed ADS Google Scholar

[12] Lin K, Chen Q, Gerhardt MR, et al. Alkaline quinone flow battery. Science, 2015, 349: 1529-1532 CrossRef PubMed ADS Google Scholar

[13] Pletcher D, Heather Thompson A. Influence of electrolyte concentration on coupled chemical reactions Part 1 Reduction of CoII(salen) in aprotic solvents. Faraday Trans, 1997, 93: 3669-3675 CrossRef Google Scholar

[14] Chen H, Armand M, Demailly G, et al. From biomass to a renewable LixC6O6 organic electrode for sustainable Li-ion batteries. ChemSusChem, 2008, 1: 348-355 CrossRef PubMed Google Scholar

[15] Tarascon JM, Armand M. Issues and challenges facing rechargeable lithium batteries. Nature, 2001, 414: 359-367 CrossRef PubMed Google Scholar

[16] Sun C, Liu J, Gong Y, et al. Recent advances in all-solid-state rechargeable lithium batteries. Nano Energy, 2017, 33: 363-386 CrossRef Google Scholar

[17] Pirnat K, Mali G, Gaberscek M, et al. Quinone-formaldehyde polymer as an active material in Li-ion batteries. J Power Sources, 2016, 315: 169-178 CrossRef ADS Google Scholar

[18] Yao M, Araki M, Senoh H, et al. Indigo dye as a positive-electrode material for rechargeable lithium batteries. Chem Lett, 2010, 39: 950-952 CrossRef Google Scholar

[19] Zhu Z, Hong M, Guo D, et al. All-solid-state lithium organic battery with composite polymer electrolyte and pillar[5]quinone cathode. J Am Chem Soc, 2014, 136: 16461-16464 CrossRef PubMed Google Scholar

[20] Lu Q, Wang X, Cao J, et al. Freestanding carbon fiber cloth/sulfur composites for flexible room-temperature sodium-sulfur batteries. Energy Storage Mater, 2017, 8: 77-84 CrossRef Google Scholar

[21] Mao O. Active/inactive nanocomposites as anodes for Li-ion batteries. Electrochem Solid-State Lett, 1999, 2: 3-5 CrossRef Google Scholar

[22] Lei Z, Wei-kun W, An-bang W, et al. A MC/AQ parasitic composite as cathode material for lithium battery. J Electrochem Soc, 2011, 158: A991 CrossRef Google Scholar

[23] Li H, Duan W, Zhao Q, et al. 2,2'-Bis(3-hydroxy-1,4-naphthoquinone)/CMK-3 nanocomposite as cathode material for lithium-ion batteries. Inorg Chem Front, 2014, 1: 193-199 CrossRef Google Scholar

[24] Huang W, Zhu Z, Wang L, et al. Quasi-solid-state rechargeable lithium-ion batteries with a calix[4]quinone cathode and gel polymer electrolyte. Angew Chem Int Ed, 2013, 52: 9162-9166 CrossRef PubMed Google Scholar

[25] Zheng S, Hu J, Huang W. An inorganic–organic nanocomposite calix[4]quinone (C4Q)/CMK-3 as a cathode material for high-capacity sodium batteries. Inorg Chem Front, 2017, 4: 1806-1812 CrossRef Google Scholar

[26] Morita Y, Agawa T, Nomura E, et al. Syntheses and NMR behavior of calix[4]quinone and calix[4]hydroquinone. J Org Chem, 1992, 57: 3658-3662 CrossRef Google Scholar

[27] Okubo M, Hosono E, Kim J, et al. Nanosize effect on high-rate Li-ion intercalation in LiCoO2 electrode. J Am Chem Soc, 2007, 129: 7444-7452 CrossRef PubMed Google Scholar

[28] Okubo M, Kim J, Kudo T, et al. Anisotropic surface effect on electronic structures and electrochemical properties of LiCoO2. J Phys Chem C, 2009, 113: 15337-15342 CrossRef Google Scholar

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