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SCIENTIA SINICA Chimica, Volume 46, Issue 6: 588-592(2016) https://doi.org/10.1360/N032015-00233

结构明确的苯基高价铜化学

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  • AcceptedDec 7, 2015
  • PublishedMar 4, 2016

Abstract

Organocopper chemistry is an indispensable part of organometallics chemistry. Because of natural abundance, cost effectiveness, and eco-friendliness, copper has been extensively used as organometallic reagents or catalysts in chemical synthesis. In contrast with the well documented organocopper(I), organocopper compounds in which copper is in higher oxidation states remain largely unexplored. For example, only a few organocopper(III) complexes have been structurally well-defined. In sharp contrast, very fewer divalent organocopper(II) compounds have been reported. This mini-review will give a summary of the recent development on structurally well-defined high-valent organocopper compounds.


Funded by

国家自然科学基金创新研究群体资助项目(21521002)


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