Facile synthesis of hollow Ti2Nb10O29 microspheres for high-rate anode of Li-ion batteries

Yong-Gang Sun; Tian-Qi Sun; Xi-Jie Lin; Xian-Sen Tao; Dong Zhang; Chen Zeng; An-Min Cao; Li-Jun Wan

doi:10.1007/s11426-017-9201-y

SCIENCE CHINA Chemistry

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SCIENCE CHINA Chemistry, Volume 61 , Issue 6 : 670-676(2018) https://doi.org/10.1007/s11426-017-9201-y

Facile synthesis of hollow Ti₂Nb₁₀O₂₉ microspheres for high-rate anode of Li-ion batteries

Yong-Gang Sun ^1,2, Tian-Qi Sun ^2,3, Xi-Jie Lin ^1,2, Xian-Sen Tao ^1,2, Dong Zhang ^1,2, Chen Zeng ⁴, An-Min Cao ^1,2,*, Li-Jun Wan ^1,2,*

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Affiliations：

1. Key Laboratory of Molecular Nanostructure and Nanotechnology and Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

2. University of Chinese Academy of Sciences, Beijing 100049, China

3. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China

4. College of Food Science & Technology, Huazhong Agricultural University, Wuhan 430070, China

* Corresponding authors (email: anmin_cao@iccas.ac.cn; wanlijun@iccas.ac.cn)

ReceivedNov 3, 2017
AcceptedDec 28, 2017
PublishedMar 2, 2018

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Abstract

Funded by

the National Natural Science Foundation of China(51672282,21373238)

the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010101)

Acknowledgment

This work was supported by the National Natural Science Foundation of China (51672282, 21373238), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDA09010101).

Interest statement

The authors declare that they have no conflict of interest.

Supplement

The supporting information is available online at http://chem.scichina.com and http://link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.

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Figure 1
SEM images of (a) the precursor of Ti-Nb-RF and (b) the calcined product of H-TNO; (c) TEM image and (d) HRTEM image of H-TNO (inset shows the FFT result of the HRTEM image).
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Scheme 1
Schematic diagram for the synthetic procedure of H-TNO (color online).
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Figure 2
(a) XRD pattern of H-TNO; (b) the crystal structure of Ti₂Nb₁₀O₂₉ (color online).
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Figure 3
(a) N₂ adsorption-desorption isotherms and (b) the pore size distribution of H-TNO (color online).
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Figure 4
(a) The first charge/discharge cures of H-TNO and S-TNO electrodes at 0.2 C; (b) long cycling performance of H-TNO and S-TNO electrodes at high current rate of 10 C; (c) comparison of the rate capability of H-TNO and S-TNO electrodes at a current rates from 1 to 100 C; (d) Nyquist plots of H-TNO and S-TNO electrodes in a frequency range of 100 kHz to 0.1 Hz.

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