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SCIENCE CHINA Chemistry, Volume 61 , Issue 9 : 1151-1158(2018) https://doi.org/10.1007/s11426-018-9278-5

FeP nanoparticles derived from metal-organic frameworks/GO as high-performance anode material for lithium ion batteries

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  • ReceivedMar 20, 2018
  • AcceptedMay 14, 2018
  • PublishedAug 3, 2018

Abstract


Funded by

the National Key R&D Program of China(2016YFB0100305)

the National Natural Science Foundation of China(51622210)

and the Fundamental Research Funds for the Central Universities(WK3430000004)


Acknowledgment

This work was supported by the National Key R&D Program of China (2016YFB0100305), the National Natural Science Foundation of China (51622210), and the Fundamental Research Funds for the Central Universities (WK3430000004).


Interest statement

The authors declare that they have no conflict of interest.


Supplement

The supporting information is available online at http://chem.scichina.com and http://link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.


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  • Figure 1

    (a) XRD patterns of the as-synthesized FeP@NC@rGO, FeP@NC, and PB@GO composites. (b) Raman spectra of FeP@NC@rGO and FeP@NC composites (color online).

  • Figure 2

    (a) Full XPS spectrum of as-synthesized FeP@NC@rGO. XPS spectra of (b) Fe 2p, (c) P 2p, and (d) high-resolution XPS spectra of C 1s of FeP@NC@rGO.

  • Figure 3

    (a) SEM image of PB@GO. (b) SEM image of FeP@NC@rGO. (c) TEM image of PB@GO. (d) TEM image of FeP@NC@rGO. (e) HRTEM image of FeP@NC@rGO. (f–i) EDS elemental mappings of FeP@NC@rGO (color online).

  • Figure 4

    (a) N2 adsorption-desorption isotherms of FeP@NC@rGO. (b) The corresponding pore size distributions (color online).

  • Figure 5

    (a) CV curves of FeP@NC@rGO as anode for LIBs at a scanning rate of 0.1 mV s−1. (b) Galvanostatic charge/discharge profiles of the initial three cycles of FeP@NC@rGO electrode. Cycling performance of FeP@NC@rGO and FeP@NC electrodes at (c) 100 mA g−1 and (d) 1000 mA g−1. (e) Rate capability of FeP@NC@rGO and FeP@NC electrodes. (f) Nyquist of FeP@NC@rGO obtained by applying a sine wave, fitted with the equivalent circuit in the inset (color online).