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SCIENCE CHINA Chemistry, Volume 63 , Issue 9 : 1175-1176(2020) https://doi.org/10.1007/s11426-020-9782-2

Towards precise synthesis of functional polymers by iterative electropolymerization

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  • ReceivedMay 24, 2020
  • AcceptedJun 2, 2020
  • PublishedJun 15, 2020

Abstract

There is no abstract available for this article.


Interest statement

The authors declare no conflict of interest.


References

[1] Yamago S. Chem Rev, 2009, 109: 5051-5068 CrossRef PubMed Google Scholar

[2] Zhang J, Wang J, Wei C, Wang Y, Xie G, Li Y, Li M. Nat Commun, 2020, 11: 2530 CrossRef PubMed Google Scholar

[3] Zhang J, Du J, Wang J, Wang Y, Wei C, Li M. Angew Chem Int Ed, 2018, 57: 16698-16702 CrossRef PubMed Google Scholar

[4] Li M. Chem Eur J, 2019, 25: 1142-1151 CrossRef PubMed Google Scholar

[5] Zhong YW, Yao CJ, Nie HJ. Coord Chem Rev, 2013, 257: 1357-1372 CrossRef Google Scholar

  • Figure 1

    Rapidly sequence-controlled electrosynthesis of coordination polymers. (a) Chemical structures of monomers. They are divalent metal complexes with two PF6 counter anions, which are omitted in the figure for the sake of clarity. (b, c) Electrochemical oxidative and reductive couplings for iterative synthesis. (d) Schematic representation of polymers assembled on indium-doped tin oxide (ITO) by iterative electrosynthesis. (e–g) UV-Vis absorption and (h–j) CV spectral changes monitored during electrosynthesis of polymers of different monomer sequences [2] (color online).